Yes, but usually slowly.
At one time there was no Oxygen in the atmosphere, (and quite a bit of methane)
and a little less than a billion years ago there was more than 25 % O2 (age of the giant insects ... with lots of plants on land.)
It is simpler because the amount of water vapor in the air can change.
It is simpler because the amount of water vapor in the air can change.
Go to images.google.com and search for gases in the atmosphere.
Nitrogen (about 78%) and oxygen (about 21%).
line graph
When did people start to change the atmosphere by releasing gases
Cirle Graph.
Over long periods of time the concentrations of some gasses such as oxygen and carbon dioxide do change. Water vapor is even more variable, often changing on a daily or hourly basis.
That's because water vapor is so variable in its concentration in the atmosphere.
The atmosphere of the earth is the layers of air that surround the Earth. They contain nitrogen, oxygen, carbon dioxide, water vapor, and small percentages of other gases.
There are more than two gases in the atmosphere. You need to specify the ones you are asking about.
A pie chart is often the best type of graph to show percentages.