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It certainly can. It can also occur at lower or higher temperatures.

15 MK is roughly the core temperature of the Sun. At this temperature the PP chain is dominant, with the CNO cycle contributing roughly an order of magnitude less energy. At around 17 MK the two are roughly equal, and at higher temperatures the CNO cycle becomes dominant.

Much below 4 MK, you're not normally going to get significant fusion (there are "cold fusion" techniques that can happen at much lower temperatures, such as muon-catalysed fusion, but these aren't net producers of energy: it takes more energy to make the muons than you can get out of the resultant fusion reaction).

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Q: Does nuclear fusion occur at 15000000c?
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