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iron doesnt oxidize when oxygen binds to haemoglobin. instead ion induced dipole attraction is present between iron and oxygen.

source: my teacher and there's a bit about this on wikipedia. search for haemoglobin there.

JAWAD REHMAN

M A STUDENT

In formation of oxy-hemoglobin, oxygen does not combine with two positive

valences of the ferrous iron in the hemoglobin molecule. Instead, it binds loosely with

one of the six "coordination" valences of the iron atom. This is an extremely loose bond

so that combination is reversible. Furthermore, the oxygen does not become ionic oxygen but is carried as molecular oxygen to the tissue where it is released into the tissue fluids in the form of dissolved molecular oxygen rather than ionic oxygen. This explains why blood does not rust despite having the all necessary substrates for the formation of the rust.

Tahi

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Q: Does the oxygen oxidize the iron when both are attached to the heme in hemoglobin?
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