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Actually Murphy's law has been suggested (humorously) as "the fourth law of thermodynamics".

It is only peripherally related the the second law. One of the implications of the second law is that an increase in disorder in the universe is a consequence of natural processes. Some have suggested that Murphy's law (If any thing can go wrong, it will.) is an example of this. Strictly speaking - this is quite different from the 2nd law but when someone screws up, it sure does tend to cause a lot of disorder!

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Q: How are the second law of thermodynamics and Murphys law related?
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