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Not exactly sure what you're asking but I'll give it a shot. Intermolecular forces do not change when a substance undergoes a phase change, such as when something goes from a solid to a liquid. The same intermolecular forces that existed when something was a solid still exist when it changes to a liquid, and vice versa. Its just that with the addition of an external factor (most commonly an increase in temperature) a substance is able to overcome the attractive forces in the solid and break apart into a liquid or when a liquid turns into a gas. For when something freezes or condenses the opposite happens, an external factor (most commonly a decrease in temperature) causes a given substance to be attracted to itself more strongly and then the substances comes together as either a liquid or a solid.

In summary: The forces do not change. Just how much the forces effect the overall substance changes.

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12y ago
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8y ago

The intermolecular forces within a solid are stronger than the similar forces in a liquid or a gas; as a consequence solids are harder, denser, having generally high melting and boiling points.

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Q: How do the intermolecular forces within a solid differ from that of a gas or liquid How does this explane a solid behavior?
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