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In order to increase the rate of a reaction and to decrease the magnitude of the activation energy, compounds containing transitional elements or their oxides are used.

One of the fundamental behaviours of these metals are heterogenous catalysis. In this procedure, the 3d and 4s orbitals are usually free of electrons, and it allows to create bonds (with higher covalent character) with reactants, which will make the reactants to collide in the correct angle more efficiently.

Usage of these compounds in the reactions of gases is a special feature.

Given below a list of compounds used as catalysts and their usage.

  1. Vanadium pentoxide or vanadium metal - To convert sulphur dioxide into sulphur trioxide in the manufacture of Sulphuric(VI) Acid.
  2. Iron metal - Manufacture of ammonia by Haber's process
  3. Chromium(III) Oxide or Zinc(II) Oxide - Manufacture of methanol using carbon monoxide
  4. Titanium metal and compounds - To synthesize polymers out of alkenes (e.g. polythene).
  5. Nickel metal - To saturate unsaturated hydrocarbons
  6. Cobalt compounds - To synthesize carbonyl compounds
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Q: How do transitional element compounds behave as catalysts?
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