Serpentine belts use an pulley to keep tension on the belt. You need a breaker bar; attach to the tension pulley and turn the nut. One way will not move and the other way will loosen the belt. It will usually then just slide off that pulley and then come off all the rest.
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around 200
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You can change the serpentine belt by loosening the tensioner pulley. When the tensioner pulley is loose and the serpentine belt will become loose. Put the new serpentine belt on and tighten the tensioner pulley.
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a pully underneath the alternator moves with an end wrench. turn the nut clockwise and the belt will loosen up