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Hot water is the worst possible thing for stains. Hot water will cause the stain to set, making it permanent. If you spill coffee, spaghetti sauce, chocolate, anything like that on your clothes, you need to rinse it immediately with ice water. Then use a pre-treater, like Oxi-Clean or those Tide stain pens.
THEN you put it in the wash. If the ice water and the pre-treater get the stain completely out, then you can use a regular setting. If the stain is still visible at all, then use the cold water setting.
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