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The simplest method would be to mount a pressure gauge onto the chamber, then to observe whether the reading changes.
It should remain at "zero" indicated gauge pressure. If your instrumentation is relative to atmospheric pressure, it would be a "minus" pressure and would vary with local atmospheric pressure.
For very accurate readings, you would need something more sophisticated, such as an ionisation gauge.
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Where could one find a vacuum chamber?
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vacuum leakTo
