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To the wife only, just as Mrs. She has no title of her own.
The best way to address your letter to a Minister is to Reverend and Mrs. _______
Govenor and Mrs. Beebe
You can address a retired colonel as "Colonel (Last Name)" and his wife as "Mrs. (Last Name)" or "Colonel (Last Name) and Mrs. (Last Name)" in the salutation of a letter.
What is the proper etiquette to addressing a Reverend in a letter?
To;The Reverend and Mrs (Insert name)
Captain and Mrs.....
You would use the first name of the husband and the first name of the wife. This is how you address a Japanese married couple through a letter.
You write “Dr and Mrs. Smith”
Baroness
Baroness