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The piplup boat is during the Pokemon parade at wifi(the bottom of poke center)
You cannot catch Piplup in any game.
no
Piplup
in the begining of the game If you want a piplup and a turtwig or chimchar I suggest trading.
when you start the game you can choose a piplup or chimchar or tutwig.
Put a membner of the piplup family in the daycare together with a ditto.
Piplup is a starter Pokémon so it cannot be caught.
You can get a Piplup on Heartgold by trading it from your Diamond/Pearl/Platinum games.
Piplup,Chimchar,Turtwig
turtwig chimchar piplup
you have to have a ditto and prinplup or empoleon