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Best way would probably be to use a multimeter or voltmeter.

Turn the meter on to volts DC and connect the probes to the battery terminals, if the voltage is shown as a negative, then switch the meter's probes around at the battery end so it shows the voltage as a positive reading on the meter.

Mark the positive and negative terminals on the battery after this.

Some car batteries have the negative terminal as the small post, but on some as the big post.

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Q: How do you identify battery terminals without any marking?
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