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Obviously, you can't.

If you don't have a jigger/shot glass/measuring cup (or just don't want to mess around with one), you can estimate by pour time. Bartenders fit open liquor containers with spouts that control pour rate such that if you turn the bottle over while you count to three, as long as you always count at the same rate you'll always get about the same amount of alcohol. This is faster than actually measuring and reasonably accurate. If you watch a show like "Bar Rescue", often times the mixologist will be shown explaining to the bartenders how to make the new cocktails using pour times: "Pour tequila for a three-count, pour triple sec for a one-count, add the juice of a lime, shake and pour it over ice".

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Q: How do you measure liquor without measuring it?
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