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If you want to thaw out frozen STUFFED peppers, like bell peppers, I would move the peppers from the freezer to the refrigerator the day before I intended to cook them. Anything that thick will require a while to defrost, and it shouldn't be left out that long. If you want to thaw out something as big as a poblano, if its been stuffed, I'd also defrost in the fridge. For smaller, unstuffed chilis like ancho poblanos and the like, I think you could just pull them out 30 - 60 minutes beforehand and defrost them at room temperature.

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13y ago
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Q: How do you thaw out frozen hot peppers without being mushy?
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