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How is density influenced by crystallinity?

Updated: 8/18/2019
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11y ago

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higher crystallinity in a polymer = lower density

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Q: How is density influenced by crystallinity?
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Crystals are type of solid state bodies whose structural order are well defined and have a unique lattice structures. There is a perfect distance between the various layers in its structure. Crystallinity has big influence on the hardness, density of the body. Non- Crystalline substances are the ones who lack the structural order and do not posses the well defined lattice structure. They tend to have lower density and low melting point as there atoms are scattered. Crystals have high tensile strength while the non crystals are not.


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What are the factors that influence crystallinity?

In general it can be said that the most important factor affecting the crystallinity is the structure of the components used in polymer synthesis. If the polymer synthesized has a very symmetrical structure, then we can say that a highly crystalline material will form. The tacticity of the polymer is also important factor affecting the crystallinity. If the components are reacting in an ordered way, like syndiotactic PET, the material will be highly crystalline. But if the PET is atactic then it will be highly amorphous,even if the components of the polymer are the same.


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