Crystals are type of solid state bodies whose structural order are well defined and have a unique lattice structures. There is a perfect distance between the various layers in its structure. Crystallinity has big influence on the hardness, density of the body. Non- Crystalline substances are the ones who lack the structural order and do not posses the well defined lattice structure. They tend to have lower density and low melting point as there atoms are scattered. Crystals have high tensile strength while the non crystals are not.
A higher degree of polymerization generally leads to higher crystallinity in polymers. Longer polymer chains can pack together more closely in an organized manner, increasing the likelihood of crystalline regions forming. This results in a higher degree of ordered molecular structure, leading to increased crystallinity in the polymer.
Branched polymers have side chains branching off from the main polymer chain, giving them a more complex structure. This branching increases their flexibility and reduces their crystallinity compared to linear polymers, which have a straight chain structure. Branched polymers also have lower viscosity and higher elasticity than linear polymers.
Polymers can be modified by adding additives, blending different polymers together, controlling the molecular weight, crosslinking, or changing the copolymer composition. These modifications can alter the mechanical properties, thermal stability, or chemical resistance of the polymer.
In general it can be said that the most important factor affecting the crystallinity is the structure of the components used in polymer synthesis. If the polymer synthesized has a very symmetrical structure, then we can say that a highly crystalline material will form. The tacticity of the polymer is also important factor affecting the crystallinity. If the components are reacting in an ordered way, like syndiotactic PET, the material will be highly crystalline. But if the PET is atactic then it will be highly amorphous,even if the components of the polymer are the same.
Crystallinity in a polymer can lead to decreased flexibility and impact resistance. It may also make the material more prone to stress cracking. Additionally, the presence of crystalline regions can affect the transparency and processability of the polymer.
A higher degree of polymerization generally leads to higher crystallinity in polymers. Longer polymer chains can pack together more closely in an organized manner, increasing the likelihood of crystalline regions forming. This results in a higher degree of ordered molecular structure, leading to increased crystallinity in the polymer.
1. Chain length 2. Plasticizers 3. Cross linking 4. Crystallinity
Branched polymers have side chains branching off from the main polymer chain, giving them a more complex structure. This branching increases their flexibility and reduces their crystallinity compared to linear polymers, which have a straight chain structure. Branched polymers also have lower viscosity and higher elasticity than linear polymers.
Water soluble polymers are polymers that will dissolve in water.
higher crystallinity in a polymer = lower density
In synthetic polymers, syndiotactic refers to a specific arrangement of monomer units in a polymer chain where the side groups alternate positions on opposite sides of the main chain. This arrangement can lead to unique material properties, such as increased stiffness and crystallinity, compared to atactic or isotactic polymers.
Branched polymers have side chains or branches extending from the main polymer chain, giving them a more complex and three-dimensional structure. This branching can affect the physical properties of the polymer, such as its flexibility, crystallinity, and viscosity. Branched polymers often exhibit different properties compared to their linear counterparts, making them useful in various applications, such as in adhesives and viscosity modifiers.
High polarity would give higher crystallinity and thus higher melting point. High degrees of cross-linking will mean the polymer may not even melt but char.
Polymers can be modified by adding additives, blending different polymers together, controlling the molecular weight, crosslinking, or changing the copolymer composition. These modifications can alter the mechanical properties, thermal stability, or chemical resistance of the polymer.
In general it can be said that the most important factor affecting the crystallinity is the structure of the components used in polymer synthesis. If the polymer synthesized has a very symmetrical structure, then we can say that a highly crystalline material will form. The tacticity of the polymer is also important factor affecting the crystallinity. If the components are reacting in an ordered way, like syndiotactic PET, the material will be highly crystalline. But if the PET is atactic then it will be highly amorphous,even if the components of the polymer are the same.
Two polymers with the same repeating subunit can exhibit vastly different properties due to variations in their molecular arrangement, such as chain length, branching, and cross-linking. The physical structure, including crystallinity and amorphous regions, can influence their mechanical strength, flexibility, and thermal stability. Additionally, the way the polymers interact with their environment, such as solvent compatibility and temperature response, can also lead to differing characteristics despite having identical subunits. Thus, the overall properties are determined not just by the chemical composition but by the polymer's architecture and molecular interactions.
they are called polymers