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Melting points are determined by the strength of interaction between molecules in a solid. The greater the force of interaction, the higher the melting point.

Molecular interactions are the result of the attraction between partially charged molecules or ions in a solid. Alkenes have little or no charge; they are nonpolar. In order for alkenes to stick to each other in a solid, they need to have partial charge induced randomly. This is known as London Dispersion Force.

The probability of a partial charge occurring is increased when the size of a molecule's electron cloud increases. Bigger alkenes have bigger electron clouds, and thus have more powerful London dispersion force. More intermolecular force means higher melting points.

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12y ago
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11y ago

As lenght of the carbon chain increases, the density increases.

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Q: How the melting point of alkenes can be increase by increasing molecular mass?
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