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network molecular
Phosphorus - covalent network Argon - covalent molecular
Covalent molecule
Network solids are held together by covalent bonds to each other. They're usually very hard and have high melting points, and are also poor heat and electrical conductors. Think of diamond and graphite. These are covalent network solids. Molecular solids, on the other hand, are molecules held together by weak intermolecular forces (such as dipole-dipole, ion-dipole, or London dispersion forces). These are usually soft with low melting points, and are also poor conductors of heat and electricity. Some examples of molecular solids would be carbon dioxide and benzene. The way I think about it, to help it make more sense to me, is that in covalent network solids, each atom is BONDED to all the other atoms around it. In molecular solids, you have completely separate molecules that are just weakly held together by intermolecular forces, they're not actually bonded to each other.
Network Solids are atomic solids that contain strong directional covalent bonds to form a solid that might be best viewed as a giant molecule.
network molecular
Phosphorus - covalent network Argon - covalent molecular
Covalent molecule
HNO3 (nitric acid) is ionic.
ionic, covalent (molecular and network), and metallic
Network solids are held together by covalent bonds to each other. They're usually very hard and have high melting points, and are also poor heat and electrical conductors. Think of diamond and graphite. These are covalent network solids. Molecular solids, on the other hand, are molecules held together by weak intermolecular forces (such as dipole-dipole, ion-dipole, or London dispersion forces). These are usually soft with low melting points, and are also poor conductors of heat and electricity. Some examples of molecular solids would be carbon dioxide and benzene. The way I think about it, to help it make more sense to me, is that in covalent network solids, each atom is BONDED to all the other atoms around it. In molecular solids, you have completely separate molecules that are just weakly held together by intermolecular forces, they're not actually bonded to each other.
Network Solids are atomic solids that contain strong directional covalent bonds to form a solid that might be best viewed as a giant molecule.
These are giant molecular lattice structures. This implies that strong covalent bonding holds their atoms together in a highly regular extended network. The bonding between the atoms goes on and on in three dimensions. Melting requires the separation of the species comprising the soild state, and boiling the separation of the species comprising the liquid state. Because of the large amount of energy needed to break huge numbers of covalent bonds, all giant covalent network structures have high melting points and boiling points and are insoluble in water. Diamond, graphite (allotropes of carbon) and quartz (silicon(IV) oxide, SiO2) are examples.
There are two molecular network structures that result in high melting points. The covalent structure of carbon forms rigidity of diamond. A diamond can in fact boil but it requires an extreme temperature because of this structure. Salt (NaCl) has a rigid ionic lattice structure between its sodium and chloride atoms. This gives salt a melting point of some 801 degrees Celsius.
It can be categorised into -Ionic -Covalent molecular -Metallic -Covalent network
Diamond is a covalent network solid, and those types of compounds have higher melting points than other types of compound.
Sand (SiO2) is a network covalent solid. It's considered to be extremely strong with relatively high melting points (>1550'C). It is made by atoms making multiple bonds with other atoms in the "network". To compare, another example of a network covalent solid is diamonds.