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As you state NaCl is the salt of a strong acid and a strong base and should have a neutral pH. However, several sites make the claim that the pH is in the range of 4.5-5.5. It's possible for a neutral solution to have a pH of something other than 7. pH is dependent on temperature, for example, but not that strongly; I can't find the exact ionization constant for water at 37oC, but by interpolation it's going to be somewhere around 13.6. It may be that the NaCl is promoting the dissociation of water to get the ionization constant to around 10; one of the statements in the discussion makes this claim.

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Q: If pH of salt water should be 7 then why does the normal saline used in iv drips have a pH of 4.5-5.5?
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