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first you have too get the rats tail from the Land Of Summons then go to the overworld and get the hovercraft with the modified airship pick it up and go near mythril and you will see island put the hovercraft down and go to the cave and you will see a man and he will ask you for it and when you give it too him he will give you adamantite which is the ore you speak of

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Q: In final fantasy 4 advanced where is the ore to get Excalibur?
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