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Water is unusual in that it expands when it freezes. There are other substances that also do this, but it's not very common.

The point of maximum density for water at standard pressure is about 277 K (that's, roughly, 39 degrees Fahrenheit). Both above and below that temperature it expands, and it also expands significantly (by about 10%) as it freezes. Most substances contract when they freeze.

The reason for this has to do with hydrogen bonding, which stabilizes a relatively expansive crystal structure for water.

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Q: In terms of thermal expansion why is water unusuel?
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