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Size matters little in identifying a good insulator, unless you mean material thickness. The breakdown strength of the insulating material affects how thick the material has to be in order to sustain a specific voltage difference without harm done to any one or thing. The breakdown strength is normally expressed as volts per unit length (aka thickness). I presume you can get the information from a science or engineering handbook or manufacturing datasheet. You need to over-design and allow extra thickness than what the paper says.

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Q: Insulators what sizes for what voltages?
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