When H and S are both positive
Use the following equation: delta G = delta H - T*deltaS. A reaction is spontaneous if delta G is negative. A reaction will always be spontaneous (under any temperature) only if the change in enthalpy (delta H) is negative and the change in entropy (delta S) is positive. If this is not the case, the reaction will only be spontaneous (negative delta G) for a range of temperatures (or could be always non-spontaneous)
A reaction is always spontaneous when the change in Gibbs free energy (ΔG) is negative. This occurs when the enthalpy change (ΔH) is negative (exothermic reaction) and the entropy change (ΔS) is positive, particularly at all temperatures. Even if ΔH is positive, if ΔS is sufficiently large and positive, the reaction can still be spontaneous at high temperatures, as the term TΔS will outweigh ΔH.
A positive value of delta G (ΔG) indicates that a reaction is non-spontaneous under standard conditions, meaning it requires an input of energy to proceed. In this case, the products have higher free energy than the reactants, suggesting that the reaction is unfavorable in its current direction. Therefore, the reaction is more likely to occur when coupled with a spontaneous process or under different conditions that favor the formation of products.
The entropy increase in this reaction.
When H and S are both positive
No, the free energy of a cell reaction is negative when the emf of the cell reaction is positive. This is because a positive emf indicates that the reaction is spontaneous and capable of performing work, resulting in a negative change in free energy.
G is always negative when H is negative and S is positive.
When H is positive and S is negative
The reaction N2 (g) + 3H2 (g) → 2NH3 (g) shows an increase in entropy because it involves an increase in the number of gaseous molecules from 2 to 4. Therefore, the entropy change for this reaction is positive.
G is always positive when enthalpy increases and entropy decreases.
G is always positive when enthalpy increases and entropy decreases.
The spontaneity of a reaction is determined by the sign of the Gibbs free energy (ΔG). If both enthalpy (H) and entropy (S) are positive, the reaction can be spontaneous at high temperatures where the TΔS term outweighs the positive ΔH term, resulting in a negative ΔG. This means the reaction will be spontaneous at elevated temperatures.
In an electrochemical reaction, the cell can be positive or negative, depending on the direction of electron flow.
Gibbs free energy (G) will always be negative for spontaneous processes at constant temperature and pressure, indicating that the reaction can occur without external input. Conversely, Gibbs free energy will be positive for non-spontaneous processes, suggesting that the reaction requires energy input to proceed. When G is zero, the system is at equilibrium, meaning there is no net change in the concentrations of reactants and products.
when H is negative and S is positive
Guys watch out the question, if your question end with positive then the answer will be An endothermic reaction that decreases in entropy. If the question end with negative then its An exothermic reaction that increases in entropy--APEX hope this help