A reaction is always spontaneous when the change in Gibbs free energy (ΔG) is negative. This occurs when the enthalpy change (ΔH) is negative (exothermic reaction) and the entropy change (ΔS) is positive, particularly at all temperatures. Even if ΔH is positive, if ΔS is sufficiently large and positive, the reaction can still be spontaneous at high temperatures, as the term TΔS will outweigh ΔH.
A reaction is always spontaneous when the change in Gibbs free energy (ΔG) is negative (ΔG < 0). This occurs when the system's enthalpy change (ΔH) is negative and the entropy change (ΔS) is positive, or when the temperature is sufficiently low to make the term TΔS (where T is temperature) less significant compared to ΔH. In summary, spontaneous reactions can be identified by a negative ΔG value, indicating that they can occur without external input.
The first of two factors that determine whether a reaction is spontaneous or non-spontaneous is entropy. The second is energy. For a reaction to be spontaneous, it must have both of these factors.
Use the following equation: delta G = delta H - T*deltaS. A reaction is spontaneous if delta G is negative. A reaction will always be spontaneous (under any temperature) only if the change in enthalpy (delta H) is negative and the change in entropy (delta S) is positive. If this is not the case, the reaction will only be spontaneous (negative delta G) for a range of temperatures (or could be always non-spontaneous)
The actual yield of a reaction product is always less than the yield from the chemical equation. This is because of error.
The reaction happens by itself.
when H is negative and S is positive
No, an exothermic reaction is not always spontaneous. The spontaneity of a reaction depends on factors such as temperature, pressure, and the entropy change of the system.
The spontaneity of a reaction is determined by the sign of the Gibbs free energy (ΔG). If both enthalpy (H) and entropy (S) are positive, the reaction can be spontaneous at high temperatures where the TΔS term outweighs the positive ΔH term, resulting in a negative ΔG. This means the reaction will be spontaneous at elevated temperatures.
Reactions are described by this equation: GD = HD - TDS where D = delta for change in values. GD < 0 spontaneous HD < 0 exothermic ; HD > 0 endothermic The first equation is Gibbs free energy. When G is negative, the reaction is spontaneous. In contrast, a positive number G is non spontaneous. The interesting thing is that spontaneous reactions can be EITHER exothermic and endothermic. Lets look at this: lets assume HD has a value of 100. This means TDS would have to be bigger than 100 in order to make GD a negative number. An endothermic reaction which has a positive H can still be exothermic. Here's another way to pose your question: Is an exothermic reaction spontaneous? Always. Is an endothermic reaction spontaneous? This can be either.
The first of two factors that determine whether a reaction is spontaneous or non-spontaneous is entropy. The second is energy. For a reaction to be spontaneous, it must have both of these factors.
Use the following equation: delta G = delta H - T*deltaS. A reaction is spontaneous if delta G is negative. A reaction will always be spontaneous (under any temperature) only if the change in enthalpy (delta H) is negative and the change in entropy (delta S) is positive. If this is not the case, the reaction will only be spontaneous (negative delta G) for a range of temperatures (or could be always non-spontaneous)
No, when H and S are both negative, the reaction will only be spontaneous below a certain temperature
A chemical equation is defined as the short-hand representation of a true chemical reaction with the help of symbols and formula.A chemical equation is formed by reactants and products.Products of a chemical equation always follow after the arrow
The Gibbs free energy will always be negative for a spontaneous reaction at constant temperature and pressure. This suggests that the reaction is thermodynamically favorable and can proceed without the input of external energy.
In this case, this is an acid-base reaction between nitric acid and ammonia. Nitric Acid is a strong acid, therefore, its hydrogen atom dissociates completely. The equation looks like this:HNO3(aq) + NH3(aq) => NH4NO3(aq)
According to the Law of Conservation Of Mass,Matter is neither created nor destroyed.It means a chemical equation show that matter is always conserved in a chemical reaction.It is shown as number of atoms both sides of the reaction before and after remains the same.
No, many exothermic reactions need the heat of activation to start the reaction. Paper, for instance, does not spontaneously burst into flame... you need to raise its temperature to the kindling point for it to burn.