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The bonding in Mo(CN)84- anion as been described in terms of sp3d4 hybridisation. The geometry of the hybrid bonds is "dodecahedral". The use of hybridisation to describe the bonding in transition metal complexes is very old school and other metods are generally used nowadays. There are some horrible pictures of this geometry on the web, try googling books for pictures.

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10y ago
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9y ago

I think XeF6 2+ is an example. Pentagonal bi-pyramidal. 5F on one plane, 1F under the plane and e- pair above. Is it works? XeF6+2 has 6 electrons pairs arround central atom Xe so it should be a regular octahedral structure with Sp3d2 hybridization, XeF6 should be pentagonal bipyramid with Sp3d3 hybridization.

Edit: Actually, it has been experimentally determined that the geometry adopted by XeF6 is a distorted octahedral geometry. It's difficult to explain without using pictures, so I'll leave it to you, to search for "distorted octahedral molecular geometry" on <insert search engine name here> (or rather, > Images).

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13y ago

After the sp3 hybridization the electrons will begin to jump to the d orbitals, rather than p orbitals.

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Q: Is SP3d3 hybridization in any atom possible?
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