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Is cyanide ion a pi acceptor ligands?

Updated: 4/28/2022
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11y ago

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Yes! It's actually a great pi acceptor.

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Q: Is cyanide ion a pi acceptor ligands?
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What are pi acceptor ligand?

ligands which can accept electrons from the metal d orbital into there anti bonding orbital such as CO, or C=C


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A pi-H ion doesn't exist. It is an error or confusion.


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What has the author Stephen Robert Ely written?

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When a positive ion (electrophile) attacks on a pi bond or partially negative carbon atom and replace H as a positive ion then it is electrophilic substitution reaction.


Does phosphorus have access to a d orbital?

Yes, phosphorous (and sulfur) have access to a d orbital. It's a bit weird (as is most chemistry), in the ground state phosphorous does not have any d orbital electrons, however, d orbital hybridization is used to explain why phosphorous can form more than the "octet" number of bonds, such as PCl5. This d orbital is also used when describing phosphorous as a pi-acceptor ligand, and the reason it can be considered a pi-acceptor ligand is because it does have access to that d orbital, which can accept the metal's e- density. Hope that helped.


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Bonding in π-complexes is strongest when both the filled π-bonding orbital of the π-bonded ligand donates TO the metal and the empty π* orbital on the ligand can accept electron density FROM the metal. A metal with a partially-filled set of d orbitals is able to participate in this synergistic mode of bonding; main group atoms virtually never have filled pπ orbitals available for donating electron density to π-complexed ligand, hence this kind of complex occurs only with transition metals.