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No, it is not a chemical reaction. Pop rocks simply melt in your mouth and release trapped CO2 (Carbon Dioxide) out into your mouth, and this release is what causes you to hear a pop, much as in popping a balloon.

A chemical reaction requires a substance to chemically change. Since the pop rock simply melts, it can always be cooled and would re-solidify.

If this were to be a chemical reaction, the enzymes in your mouth, or the water, would have to change the pop rock candy in a way that the atoms of the molecules that make it up would re-arrange to form CO2, leaving behind a totally different substance in your mouth after. Note that this change would not be easily reversible - another tell-tale method of detecting a chemical reaction.

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Q: Is pop rocks exploding on your tongue a chemical reaction?
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