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Fresh water. There will be some salt(s) and other things in solution in it, but it's a freshwater river. Water from the river is tapped to supply drinking water for some communities along the Arno. Though it's flow can be a bit irregular, it is used and processed to remove pesticides and an array of the "usual suspects" found in river waters that have to be dismissed to include the finished product in the potable water system.

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Q: Is the Arno River of Tuscany Italy a salt or fresh water river?
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