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Somewhat. The .25 cal is just bigger and hits harder. Other than shape and air pressure behind the pellet, the size and weight of the pellet has a effect on the accuracy.
OKAY look at it this way. (Pellets come in different weights.) a lightweight pellet will fly faster and farther than a heavy pellet. BUT it is more effected by crosswind than a heavy weight pellet. The Heavy pellet will fly straighter, slower and have more knockdown power than a lighter pellet.
So a .25 cal pellet is heaver and slower than a .22 cal pellet but it has more impact and a little more accurate than a .22 cal pellet.
PCP rifles come in different sizes. like .177, .20, .22, .25, 9mm, .357 cal 45 cal and 50 cal. Hitting a target with a .177 cal is like hitting it with a BB, but hit it with a 50 cal and you rip a huge hole in the target. The .177 will fly a lot farther but the 50 cal is a destroyer.
I own both a .22 cal and a .25 cal Marauder. along with several others.
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