When releasing the ball, rapidly press A. Then, when the Pokemon gets in the ball, hold B.
cheating
Not without hacking.
you can't
you can't.
You can't without using cheats.
I do belive there won't be that kind of cheat, but a smart, but long way is to buy a Pokemon pearl, or diamond, then cheating on that game, then trading and having those Pokemon have master balls.
The GTS cloning glitch.
Not without cheats, but you can win them at the lottery corner if you get first prize.
It is not possible to make master balls in Pokemon Pearl version. You can get one from beating Cyrus or in the Game Corner.
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No, You have to use an AR code to buy Master Balls on any game.
No you only get one master ball in Pokemon pearl. Sorry if this has upset you.