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Why must use buffer solution in titration involving EDTA?
EDTA is Ethydiaminotetraacetic acid. In some titrations, it is best to avoid any sharp pH changes(except in acid-base titrations, of course). Buffers are the right substances to help maintain a constant pH.
Why is the pH of the medium important in edta titration?
why is the pH of the meadium important in EDTA titration
Why is magnesium sulphate added in the assay of calcium lactate?
Replacement Titration: In this method the metal, which is to be analyzed, displaces quantitatively the metal from the complex. When direct or back titrations do not give sharp end points, the metal may be determined by the displacement of an equivalent amount of Mg or Zn from a less stable EDTA complex. Mn+2 + Mg EDTA---> 2 Mg+2 + Mn EDTA-2 Mn displaces Mg from Mn EDTA solution. The freed Mg metal is then directly titrated with a standard EDTA solution. In this method, excess quantity of Mg EDTA chelate is added to Mn solution. Mn quantitatively displaces Mg from Mg EDTA chelate. This displacement takes place because Mn forms a more stable complex with EDTA. By this method Ca, Pb, Hg may be determined using Eriochrome blackT indicator.
Why is a titration important?
Titrations are used to find the unknown concentration through an addition to a solution.
What are the applications of complexometric titration?
The Applications of Complexometric Titrations are as follows:1. Direct Titration: It is the simplest and the most convenient method in which thestandard solution of EDTA is slowly added to the metal ion solution till the endpoint is achieved. It is similar to simple acid-base titrations. For this method tobe useful the formation constant must be large and the indicator must provide avery distinct color change as mentioned earlier. Further we need standardizedsolution of EDTA and sometimes auxiliary complexing agents may be required.Some important elements which could be determined directly by thecomplexometric titration are Cu, Mn, Ca, Ba, Br, Zn, Cd, Hg, Al, Sn, Pb, Bi, Cr,Mo, Fe, Co, Ni, and Pd, etc. However, the presence of other ions may causeinterference and need to be suitably handled.2. Back Titration: In this method, an excess of a standard solution of EDTA isadded to the metal solution being determined so as to complex all the metal ionspresent in the solution. The excess of EDTA left after the complex formationwith the metal is back titrated with a standard solution of a second metal ion.This method becomes necessary if the analyte precipitates in the absence ofEDTA or reacts too slowly with EDTA, or it blocks the indicator. For example,determination of Mn is done by this method because a direct titration is notpossible due to precipitation of Mn (OH)2. The excess EDTA remaining aftercomplexation, is back titrated with a standard Zn solution using Eriochromeblack T as indicator. However, one has to ensure the standard metal ion shouldnot displace the analyte ion from their EDTA complex.3. Replacement Titration: When direct or back titrations do not give sharp endpoints or when there is no suitable indicator for the analyte the metal may bedetermined by this method. The metal to be analyzed is added to a metal-EDTAcomplex. The analyte ion (with higher Kf′) displaces EDTA from the metal andthe metal is subsequently titrated with standard EDTA. For example, in thedetermination of Mn an excess of Mg EDTA chelate is added to Mn solution.The Mn ions quantitatively displace Mg from Mg-EDTA solution because Mnforms a more stable complex with EDTA.Mn+ + MgY2 - (MY)(n - 4)+ + Mg2+The freed Mg metal is then directly titrated with a standard solution of EDTAusing Eriochrome black T indicator. Ca, Pb and Hg may also be determined bythis method.4. Indirect Titration: Certain anions that form precipitate with metal cations anddo not react with EDTA can be analyzed indirectly. The anion is firstprecipitated with a metal cation and the precipitate is washed and boiled with anexcess of disodium EDTA solution to form the metal complex.Mn+ + H2Y2 - (MY)(n - 4)+ + 2H+The protons from disodium EDTA are displaced by a heavy metal and titratedwith sodium alkali. Therefore, this method is also called alkalimetric titration.For example, barbiturates can be determined by this method.
What is Patton and reeder's reagent?
A useful indicator for calcium titrations with EDTA in the presence of magnesium.
Why must use buffer solution in titration involving EDTA?
EDTA is Ethydiaminotetraacetic acid. In some titrations, it is best to avoid any sharp pH changes(except in acid-base titrations, of course). Buffers are the right substances to help maintain a constant pH.
Why is the pH of the medium important in edta titration?
why is the pH of the meadium important in EDTA titration
What is use of Versene in inorganic chemistry?
Versene is a trade name for a chelating agent, a sodium salt of EDTA, ethylenediaminetetraacetic acid. This molecule is a polydentate ligand with 6 points where it can coordinate to a central metal ion. It binds readily to many cations and is used in the laboratory in complexometric titrations. It has many applications in for example medicine and industry.
Why is magnesium sulphate added in the assay of calcium lactate?
Replacement Titration: In this method the metal, which is to be analyzed, displaces quantitatively the metal from the complex. When direct or back titrations do not give sharp end points, the metal may be determined by the displacement of an equivalent amount of Mg or Zn from a less stable EDTA complex. Mn+2 + Mg EDTA---> 2 Mg+2 + Mn EDTA-2 Mn displaces Mg from Mn EDTA solution. The freed Mg metal is then directly titrated with a standard EDTA solution. In this method, excess quantity of Mg EDTA chelate is added to Mn solution. Mn quantitatively displaces Mg from Mg EDTA chelate. This displacement takes place because Mn forms a more stable complex with EDTA. By this method Ca, Pb, Hg may be determined using Eriochrome blackT indicator.
What is the method for making mordant black 2 indicator?
mordant black 2 is used as an indicator in comleometric titrations, usuall against Di Na EDTA Solution. the indicator is mixed with NaCl/ KI in appropriate quantity...
Why is a titration important?
Titrations are used to find the unknown concentration through an addition to a solution.
What are the applications of complexometric titration?
The Applications of Complexometric Titrations are as follows:1. Direct Titration: It is the simplest and the most convenient method in which thestandard solution of EDTA is slowly added to the metal ion solution till the endpoint is achieved. It is similar to simple acid-base titrations. For this method tobe useful the formation constant must be large and the indicator must provide avery distinct color change as mentioned earlier. Further we need standardizedsolution of EDTA and sometimes auxiliary complexing agents may be required.Some important elements which could be determined directly by thecomplexometric titration are Cu, Mn, Ca, Ba, Br, Zn, Cd, Hg, Al, Sn, Pb, Bi, Cr,Mo, Fe, Co, Ni, and Pd, etc. However, the presence of other ions may causeinterference and need to be suitably handled.2. Back Titration: In this method, an excess of a standard solution of EDTA isadded to the metal solution being determined so as to complex all the metal ionspresent in the solution. The excess of EDTA left after the complex formationwith the metal is back titrated with a standard solution of a second metal ion.This method becomes necessary if the analyte precipitates in the absence ofEDTA or reacts too slowly with EDTA, or it blocks the indicator. For example,determination of Mn is done by this method because a direct titration is notpossible due to precipitation of Mn (OH)2. The excess EDTA remaining aftercomplexation, is back titrated with a standard Zn solution using Eriochromeblack T as indicator. However, one has to ensure the standard metal ion shouldnot displace the analyte ion from their EDTA complex.3. Replacement Titration: When direct or back titrations do not give sharp endpoints or when there is no suitable indicator for the analyte the metal may bedetermined by this method. The metal to be analyzed is added to a metal-EDTAcomplex. The analyte ion (with higher Kf′) displaces EDTA from the metal andthe metal is subsequently titrated with standard EDTA. For example, in thedetermination of Mn an excess of Mg EDTA chelate is added to Mn solution.The Mn ions quantitatively displace Mg from Mg-EDTA solution because Mnforms a more stable complex with EDTA.Mn+ + MgY2 - (MY)(n - 4)+ + Mg2+The freed Mg metal is then directly titrated with a standard solution of EDTAusing Eriochrome black T indicator. Ca, Pb and Hg may also be determined bythis method.4. Indirect Titration: Certain anions that form precipitate with metal cations anddo not react with EDTA can be analyzed indirectly. The anion is firstprecipitated with a metal cation and the precipitate is washed and boiled with anexcess of disodium EDTA solution to form the metal complex.Mn+ + H2Y2 - (MY)(n - 4)+ + 2H+The protons from disodium EDTA are displaced by a heavy metal and titratedwith sodium alkali. Therefore, this method is also called alkalimetric titration.For example, barbiturates can be determined by this method.
What is EDTA titration of Water?
It one of the titrations method to determine the permanent and temporary hardness of water. Procedure; step 1: standardise the edta solution step 2: titrate against the hard water mixed with ebt until the colour changes from wine red to blue. Then we can caluclate the normality using the formula (n1) *(v1)=(n2)*(v2). Posted by Krishna kanth yenumula.
Why is the choice of indicator less important for strong acid base titrations?
because of the relative density of carbon
What is titration and what is the purposeof titration?
Titration is the process of determining the concentration of a substance of a given solution using a known reagent. So types of titrations are neutralization titrations, red-ox titrations, gravimetric titrations and colorimetric titrations. According to the reagents available, the best type of titration should be determined.
Why ph8 is maintained during isolation of plasmid?
EDTA is dissolved only at pH8. EDTA serves as an important chelating agent to kill the contaminating DNAses. Also this is close to the physoological pH which is pH7.
