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Many chat sites have a special area for 'adult' topics. These rooms are often 18+ because they discuss topics not suited for a younger audience. There are also special sites that focus solely on adult chat rooms.
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Depends what you mean by 'best'. If you want a clean adult social network and chat site then you would need to research online for only those that fit that description. AOL have many good, clean, decent chat rooms. At AOL there are hobby or interest chat rooms and there are age group chat rooms. There are also chat room moderators to make sure that everything runs pleasantly. The chat rooms are all free to use.
Adult chat rooms can only keep children out by asking their age and denying access if their age is lower than 18. There is no better system available to use.
Some examples of popular adult chatrooms are Chat Avenue, Mademan and Adult Chat. Singles-Chat is a chatroom for those seeking relationships. Chat-room is one of the largest chat sites in the world. Chat Open has been around the longest. You can check out those sites and find the one that suits your needs.
The chat rooms will be of clean content. If you are worried about "trolls" or scavengers, the christian chat rooms are your best bet. Chat rooms are getting to the point where it's all about sexual content, but you can avoid this by staying in christian chat rooms.
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There are many chat rooms available, and HiHellobye is among the best chatting websites. This platform offers chat rooms for various languages and countries.
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There are many chat rooms available, however, you have not specified the theme of the chat room. I would need additional information in order to direct you to the best rooms that have the right clientele.