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The C and K generally makes the same sound but for which one to use depends on the following letters. If the following letter is E, I or Y, then we use a K instead because if we use a C, the following letters would soften the C into an S sound. If the following letter is anything else, then we can use a C, because it'll remain a hard C and this is quite usual to use.

Things doesn't always follow the rules and there are some rule-breaker exceptions. Sometimes, we use a K although the following letters won't soften the C like "karma", "krill", "krypton", "koala", "kosher", "Korea", "kangaroo", "Kansas", etc. The K is generally used if the following letters would soften the C, otherwise we would use a C instead.

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Q: What are the rules for using C or K?
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