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The color of chromate (yellow) and dichromate (orange) comes from the chromium. In particular from the arrangement of electrons in the 3d-sublevel.

You were probably taught that the d-orbitals are all at the same energy, and that's true if there were not other atoms attached to chromium. Since chromium is in a polyatomic ion which has water molecules attached to it, there is some splitting of the energy levels of the chromium's d-orbitals and it is the difference in these two energy levels that absorbs certain wavelengths of light and not others.

The light that is not absorbed is orange, which is what you see when you look at solutions of the dichromate ion.

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Q: What atom makes potassium dichromate orange?
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Why potassium dichromate is orange red in color?

The orange color of potassium dichromate is caused by the movement of an electron to a vacant d-orbital in the manganese atom. The transition occurs when the chemical is in the presence of light. This is confirmed by the empty 3d-orbital in chromium.


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Potassium dichroamte is K2Cr2O7, in the dichroamte ion both Cr atoms have an oxidation number of +6.


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Potassium is an element, so the only atom in potassium is potassium.


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An ordinary atom of potassium has no charge.An ionized atom of potassium typically has a +1 charge.Different things.


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