Ther are really to many probable causes to even start diagnosing with out more info.Really need a tech to look at it,or understand how it works and have equipment to diagnose yourself.But to answer your question ,Something in your system is not operating the way it is supposed to.
You probably have a low refrigerant level.
The chemical in the air conditioning unit needs replaced.
Most likely the rear expansion tube or valve is defective.
Your AC is not working. Common causes are: lack of freon broken belt compressor failed
your car ac will only blow hot air when there coolannt in the car is finished or the car is oveerheated.
clean the part which is in front by opening it . it is the part which sucks hot air
No. The thermostat is not likely to be the cause.
refill the a/c, it will blow hot air with no refrigerant in the vehicle.
"http://wiki.answers.com/Q/Why_does_the_rear_ac_in_97_chevy_venture_blow_hot_air_when_the_front_ac_blows_cool_air"
why does ac blow warm air? why does ac blow warm air?
you might need to refill the freeon
Make sure the radiator fan is turning on when the AC is running.