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What factors that can cause a difference between experimental and reported values of electrode potential?
Wiki User
∙ 15y ago
1.Concentration of ions-The theoretical values apply for 1.00 M SOLUTIONS ONLY.
2.Pressure of gas(if any)-under standard conditions,any gas must be at a pressure of 1 atm.this value may be different in practice.
3.Temperature-298 K is the temperature at which theoretical vlues have been recorded.
4.Precipitation-if one of the ions is precipitated due to another one,the equilibrium is disturbed and the electrode value is changed.This happens in the lead-acid battery of vehicles,where lead sulphate is precipitated.
Wiki User
∙ 15y ago
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