In 1931, German chemist and physicist Erich Hückel proposed a theory to help determine if a planar ring molecule would have aromatic properties. His rule states that if a cyclic, planar molecule has 4n+2 π electrons, it is considered aromatic.
the rule is that if the number pi electrons is equal to 4n plus 2,where n equals 0,1,2,3,..............,the system will be aromatic,otherwise not.
A cyclic ring molecule follows Hückel's rule when the number of its π(pi)-electrons equals 4n+2 where n is zero or any positive integer, although clearcut examples are really only established for values of n = 0 up to about n = 6A furan structure is a planar 5 membered ring with one O atom in its ring on which one pi-pair is situated. This leaves another 2 pi-pair's for two double bonds, a total of 6 (3 pi-pairs) obeys Hückel's rule for the n=1 value.Thus furan is aromatic as benzene (also n=1, 6 pi-electrons in 3 pi-pairs).[See 'Related links' just below this answer page]
indirect
Authoritarian Rule
octet rule
A rule is used to measure a distance.
Huckel's rule does not explain the structure of a molecules it simply describes that a molecule is aromatic or not, the kekule's structure for benzene agrees with Huckel's rule.
Huckel's rule is used in aromaticity by stating that monocyclic systems are aromatic. This will happen if there are delocalized electrons.
By the Huckel determinant
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No - although it has sufficient electrons to obey the Huckel rule (4n+2) pi electrons. The two olefins in the ring are cross-conjugated through the carbonyl groups. The lack of proper conjugation precludes aromaticity. The non aromaticity is evidenced by different bond-lengths around the ring
as because in case of tropylium cation extra stability arises from the attainment of aromaticity as well as extensive conjugation.It contains 6π electrons which is according to Huckel's rule indicate towards the aromatic compound as well as the system is also a resonance stabilized because of delocalisation
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No it does not obey the 4N+2 electrons... it has 4 pi electrons... it is anti aromatic however the ion is aromatic which explains its relatively low pka value of 15-16 which is on par with alcohols which are generally 16-18pka
A cyclic molecule or ion having different resonating structure follows Hückel's rule when the number of its π-electrons equals 4n+2 where n is zero or any positive integer. Example (4 x (0)) + 2 = 2 π electrons (4 x (1)) + 2 = 6 π electrons (4 x (2)) + 2 = 10 π electrons etc Taking benzene as an example, it has 3 double bonds so 6 π electrons (2 electrons for each double bond) thus it fits Huckels rule and therefore is aromatic. If the molecule is an ion and has a negative charge, the negative charge is also counted as 2 π electrons. Positive charges on a cyclic molecule are ignored.
A cyclic ring molecule follows Hückel's rule when the number of its π(pi)-electrons equals 4n+2 where n is zero or any positive integer, although clearcut examples are really only established for values of n = 0 up to about n = 6A furan structure is a planar 5 membered ring with one O atom in its ring on which one pi-pair is situated. This leaves another 2 pi-pair's for two double bonds, a total of 6 (3 pi-pairs) obeys Hückel's rule for the n=1 value.Thus furan is aromatic as benzene (also n=1, 6 pi-electrons in 3 pi-pairs).[See 'Related links' just below this answer page]