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The most common agent is Methyl tert-butyl ether, also known as methyl tertiary butyl ether and MTBE; a chemical compound with molecular formula C5H12O. MTBE is a volatile, flammable and colorless liquid that is immiscible with water. MTBE has a minty odour vaguely reminiscent of diethyl ether, leading to unpleasant taste and odour in water. MTBE is a gasoline additive, used as an oxygenate and to raise the octane number, although its use has declined in the United States in response to environmental and health concerns. In the US it has been used in gasoline at low levels since 1979 to replace tetra-ethyl lead to help prevent engine knocking. Oxygen helps gasoline burn more completely, reducing tailpipe emissions from pre-1984 motor vehicles.

Other anti-knocking compounds are available as oxygenate additives for gasoline, for example ethanol and related ethers, e.g. tert-amyl methyl ether (TAME). Ethanol has been advertised as a safe alternative by the agricultural interest groups in the USA and Europe. Its lack of toxicity is not different from MTBE, but as a polar solvent, it drives off nonpolar hydrocarbons from the gasoline, a problem that MTBE does not cause.

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14y ago
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8y ago

Knocking in gas engines is when the fuel-air mixture in the cylinder self-ignites due to compression instead of waiting on the spark plug spark to ignite it. Anti-knocking agents are substances that let's the fuel-air mixture in the cylinder be compressed more w/o self-igniting.

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Q: What is knocking and anti knocking agents?
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