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It is mold and you shouldn't eat it. Mold can penetrate the food source so even if you remove the upper layer, your product is still contaminated. When you find anything growing on food, you should generally consider it to be spoiled and discard it. There are only a couple of exceptions (mold on cheese can often be cut off, for example) but with tomato sauce, it's not usable after mold begins to grow.

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Q: What is likely to be growing in my opened refrigerated tomato sauce and is it very toxic?
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