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The indicator added to the sample is Eriochrome

Black T. Initially, the indicator will form a complex with the cations. When complexed

it is red in color. As the EDTA is added dropwise to the sample, it replaces the Erio T

and forms more stable complexes with calcium and magnesium. When the indicator is

released by the metal ions, it has a distinct blue color. Therefore, the endpoint of the

titration is marked by the color change form red to blue

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Q: What is role of eriochrome black t in zn-edta titrations?
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