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No it cannot. Sodium bicarb has a ph of 8.4. To lower ph you would need to use a dry acid (sodium bisulphate) or muriatic acid. City water is normally treated and has a ph of 7.5 but it would take a large amount of fresh water to lower the ph of a pool.

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Q: What is the Difference of sodium carbonate and sodium bicarbonate for treating swimming pool PH?
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