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The results I see are based on 1990's data, and do not include the bromine that volcano's also release (whcih also effects the ozone). What chlorine is present in the stratosphere is 3% volcano sourced, 15% methyl chloride (refrigerant 40 or R-40, CH3Cl, also used as a blowing agent) (they did not identify the source, but it does also come from natural sources including plants), and 82% manmade refrigerants, primarily CFCs. See link below for more on methyl chloride / aka. chloromethane. The total chlorine released by volcanos is in a form that is easily scrubbed from the air, so very little of what is released, ends up in the stratosphere. The same is likely true for the bromine they release.

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Q: What is the amount of chlorine gas produced by volcanoes in relation to that produced by man?
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