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The word do comes first in alphabetical order before doing.
The word scoreboard comes first in alphabetical order.
The longest word in the English language which can be written in reverse alphabetical order is nine letters long.That word is Spoonfeed.Spoonfeed means "to feed with a spoon"
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"Who" would come first in alphabetical order. In any case that one word starts with the whole spelling of another word, then the longer word will follow.
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It is the longest word where the letters are in alphabetical order
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Such an alphabetical list of English words can be found in a "Dictionary" - with new words being added as a word gains popular usage.