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why is the pH of the meadium important in EDTA titration
we standardize edta to make the soln stable complex
We usually heat KSCN Fe solution before titration with EDTA so as to produce crystalline crust forms.
1. Direct Titration In direct titration, you simply add an indicator to the solution of the metal ion and titrate with EDTA. Before starting the titration,it is needed to check that the pH of the solution to obtain a good formation constant value and on the other hand indicator colour change as well. 2.Indiract titration EDTA can be used as titrant for anions. Anions can be precipitated with suitable metal ion. Filter and wash the ppt with proper solution. Then boil in excess EDTA to complex metal ion(ppt). Back titrate to determine how much metal ion you had. 3.Back Titration In a back titration an excess of EDTA is added to the metal ion solution, and the excess EDTA is titrated with a known concentration of a second metal ion. The second metal ion must form a weaker complex with EDTA than the analyte ion so the second metal does not displace the analyte ion from its complex with EDTA. 4.Displacement titration Here the analyte is treated with an excess of a second metal bound to EDTA. The analyte ion displaces the second metal from the EDTA complex, and then the second metal is titrated with EDTA.
eriochrome blact T
why is the pH of the meadium important in EDTA titration
eriochrome black T is an indicator for EDTA titration
u can use titration with EDTA or use flame atomic absorption.. but titration with EDTA is the easiest
we standardize edta to make the soln stable complex
EDTA reacts to form so called 'one to one'-complexes with all bi- and tri-valent metal ions
We usually heat KSCN Fe solution before titration with EDTA so as to produce crystalline crust forms.
1. Direct Titration In direct titration, you simply add an indicator to the solution of the metal ion and titrate with EDTA. Before starting the titration,it is needed to check that the pH of the solution to obtain a good formation constant value and on the other hand indicator colour change as well. 2.Indiract titration EDTA can be used as titrant for anions. Anions can be precipitated with suitable metal ion. Filter and wash the ppt with proper solution. Then boil in excess EDTA to complex metal ion(ppt). Back titrate to determine how much metal ion you had. 3.Back Titration In a back titration an excess of EDTA is added to the metal ion solution, and the excess EDTA is titrated with a known concentration of a second metal ion. The second metal ion must form a weaker complex with EDTA than the analyte ion so the second metal does not displace the analyte ion from its complex with EDTA. 4.Displacement titration Here the analyte is treated with an excess of a second metal bound to EDTA. The analyte ion displaces the second metal from the EDTA complex, and then the second metal is titrated with EDTA.
eriochrome blact T
to maintain constant ph
To determine concentration of EDTA.
During a precipitation titration an insoluble precipitate is formed.Complexometric titration is a type of volumetry which use as titrants EDTA or other similar reagents.
eriochome black T