If you are referring to Pokemon Platinum, HeartGold or SoulSilver, the last move Espeon learns is Power Swap (Psychic, Status) at Level 78.
If you are referring to earlier versions of Pokemon, the last move Espeon learns is Morning Sun (Normal, Status) at Level 71.
The last move Scolipede learns is double-edge, which it learns at level 55.
The last move that sceptile learns is leaf storm.
Charizard learns a rather disappointing move called Fire Spin as its last move. It learns this move at level 64
The last move Charizard learns is Flare Blitz at level 66...
Espeon does not learn Thunder. Jolteon learns it, however.
The last move it learns is Outrage, at level 85
In Generation V, the last move Chansey learns is Double-Edge at Level 54.
The last move, in fire red, that Charizard learns is Fire Spin. That is at Level 55.
Espeon learns Phychic at Lv.64
the last move luxray knows is discharge
his/her last move is explosion at level 52
Thunder