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There is no extinct volcano or mountain that fits those exact standards. You may be looking for one of these. They each fit one of the requirements and kind of come close on others:

Nevado Ojos del Salado is a stratovolcano in the Andes on the Argentina-Chile border. It is also the highest active volcano in the world and the second highest mountain in the Western Hemisphere.

Monte Pissis is an extinct volcano in La Rioja Province, Argentina. The mountain is the third-highest in the Western Hemisphere.

Nevado Huascarán is a mountain in the Peruvianprovince of Yungay, situated in the Cordillera Blanca range of the western Andes. The highest southern summit of Huascarán (Huascarán Sur) is the highest point in Peru. Huascarán is the fourth highest mountain in the Western Hemisphere.

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Q: What is the name of a extinct volcano in Peru that is the second highest mountain in the western hemisphere?
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