There is no episode like that, Ash doesn't fall in love with anyone. Dawn doesn't like anyone either.
"Kiss Kiss Fall in Love!"
Theres a boy named Kaito whom Luchia saved for the second time in her life. They both fall in love, its shown in certain episodes that they love each other. Luchia and Kaito first kiss on episode 6.
5th
one day at the last episode of Pokemon dawn accidentally fell and ash caught her and ash looked into her eyes and gave her a kiss ash kissed her for 10 seconds after ash kissed dawn then dawn kissed ash for 10 seconds after that long kiss they both fell in love! PS:well they are both are on a cliff PS:THIS MY OWN STORY! PS:it was a windy day PS:they are looking at their badges
Duncan and Gwen kiss in episode 13 or 14 as stated in Total Drama Wikia. Most possibly in episode 13 and maybe even a second time on a later episode.
The episode that Gray and Juvia kiss in the show 'Fairy Tale' is an episode called 'Love Slide'. You can catch this episode on YouTube.
Spoiler alert for episode 3x09 They kiss beneath the mistletoe as a deal with Caroline, the Lawyer, in episode 3x09, The Santa in the Slush. Spoiler alert for episodes 6x22 and 6x23 They don't kiss again until episode 6x22, The Hole in the Heart, when they fall into bed and are understood to have sleep together after Brennan admits that she is pregnant with Booth's baby, in the next episode, 6x23, The Change in the Game.
On Episode 124
They actually kiss for the first time in the first season episode "Sunday in the Park with Fran". Then they kiss three times in the second season, in "A Star is Unborn", "When You Pish Upon a Star", and "A Kiss Is Just a Kiss".From there on in things just slowly build on each other in their relationship.
misty,may,and dawn
They fall in love in episode 31. I'm pretty sure.
i dont think he say he in love with zoey but he does kiss her