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There are no accurate pKa value of these two, extremely STRONG acids, any value of >> 1000 (up to >> 1.0*10+9) will do.

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Q: What is the pKa value for Hydroastatic acid and Periodic acid?
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Why sodium hydrogensulphate functions as an acid and look up its pKa value?

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There are two answers: bicarbonate has two pKa's - because bicarbonate can gain a proton to become carbonic acid or lose a proton to become carbonate. Two reactions; two pKa's. The pKa for bicarbonate carbonic acid reaction is 6.4 The pKa for bicarbonate carbonate reaction is 10.3 Both pKa's are temperature sensitive.


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What is the pka of sodium benzoate?

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