0
Tytrate or Analyte
Wiki User
∙ 11y ago
Mykki Balduff
T
etrate
Add your answer:
Earn +20 pts
How is an indicator used to determine the pH of a solution?
Iodine solution is an efficient indicator for starch. It will go from a light brown colour to a black colour if starch is present and will stay light brown if no starch is present. Hope this Helps!
What is the manipulated variable in a titration?
The manipulated variable would be the volume of the titrant (the thing thats being added). This is the only part of a titration that is altered. The responding variable would be the pH of the solution.
What are the applications of complexometric titration?
The Applications of Complexometric Titrations are as follows:1. Direct Titration: It is the simplest and the most convenient method in which thestandard solution of EDTA is slowly added to the metal ion solution till the endpoint is achieved. It is similar to simple acid-base titrations. For this method tobe useful the formation constant must be large and the indicator must provide avery distinct color change as mentioned earlier. Further we need standardizedsolution of EDTA and sometimes auxiliary complexing agents may be required.Some important elements which could be determined directly by thecomplexometric titration are Cu, Mn, Ca, Ba, Br, Zn, Cd, Hg, Al, Sn, Pb, Bi, Cr,Mo, Fe, Co, Ni, and Pd, etc. However, the presence of other ions may causeinterference and need to be suitably handled.2. Back Titration: In this method, an excess of a standard solution of EDTA isadded to the metal solution being determined so as to complex all the metal ionspresent in the solution. The excess of EDTA left after the complex formationwith the metal is back titrated with a standard solution of a second metal ion.This method becomes necessary if the analyte precipitates in the absence ofEDTA or reacts too slowly with EDTA, or it blocks the indicator. For example,determination of Mn is done by this method because a direct titration is notpossible due to precipitation of Mn (OH)2. The excess EDTA remaining aftercomplexation, is back titrated with a standard Zn solution using Eriochromeblack T as indicator. However, one has to ensure the standard metal ion shouldnot displace the analyte ion from their EDTA complex.3. Replacement Titration: When direct or back titrations do not give sharp endpoints or when there is no suitable indicator for the analyte the metal may bedetermined by this method. The metal to be analyzed is added to a metal-EDTAcomplex. The analyte ion (with higher Kf′) displaces EDTA from the metal andthe metal is subsequently titrated with standard EDTA. For example, in thedetermination of Mn an excess of Mg EDTA chelate is added to Mn solution.The Mn ions quantitatively displace Mg from Mg-EDTA solution because Mnforms a more stable complex with EDTA.Mn+ + MgY2 - (MY)(n - 4)+ + Mg2+The freed Mg metal is then directly titrated with a standard solution of EDTAusing Eriochrome black T indicator. Ca, Pb and Hg may also be determined bythis method.4. Indirect Titration: Certain anions that form precipitate with metal cations anddo not react with EDTA can be analyzed indirectly. The anion is firstprecipitated with a metal cation and the precipitate is washed and boiled with anexcess of disodium EDTA solution to form the metal complex.Mn+ + H2Y2 - (MY)(n - 4)+ + 2H+The protons from disodium EDTA are displaced by a heavy metal and titratedwith sodium alkali. Therefore, this method is also called alkalimetric titration.For example, barbiturates can be determined by this method.
Is The substance being dissolved in a solution is called a solvent.?
Nope - the substance being dissolved is the solute. The solution in which the substance is being dissolved - is the solvent.
How does titration of strong acid strong base differ from titration of weak acid strong base respect to quantity of base required to reach equivalent point?
There are three major differences between strong acid/strong base and weak acid/strong base titrations. For weak acid/strong base titrations: 1. The weak-acid solution has a higher initial pH. 2. The pH rises more rapidly at the start, but less rapidly near the equivalence point. 3. The pH at the equivalence point does not equal 7.00. (should be >7) In an acid-base titration, there is a 1:1 acid:base stoichiometry, so the equivalence point is the point where the moles of titrant added equals the moles of substance initially in the solution being titrated. Therefor the strength of the acid or base should not have an affect on the quantity of base required, only on the pH of the equivalence point. The number of moles of titrant and solution will have an effect on the quantity of base required.
A 0.361 molar solution of the weak acid HA with a pKa of 4.039 is titrated with a 0.163 molar solution of NaOH. What is the pH of the solution at the equivalence point of this titration?
You need to know the volume of the weak acid being titrated so you can find how many moles of base are needed to match that of the acid.
What is the operation principle of a titration?
A solution containing an element to be determined (the concentration being unknown) is titrated (adding a reagent - the titrant) with a standard solution (with a known concentration); knowing the volume of the titrant and the reaction which occur the concentration of the analyte is calculated. Titration is manual (also called volumetry) or potentiometric and is a very common method in analytical chemistry.,
Describe a method to visually detect the end point of a titration without the use of instruments?
The method used most often in chemistry labs is by use of a pH indicator in the sample being titrated. When you reach the titration point, the indicator will change colors, demonstrating the end point of the titration.
How is an indicator used to determine the pH of a solution?
Iodine solution is an efficient indicator for starch. It will go from a light brown colour to a black colour if starch is present and will stay light brown if no starch is present. Hope this Helps!
How does the equivalence point differ from the half equivalence point?
Equivalence point is reached when Reactants react at Stoichiometric ratios and reach the Endpoint so that no more of the solution being titrated is found.Eg: Strong base + Strong Acid: HCL+NaOH--> NaCl+H2O1mol of Hcl Requires 1 mol of NaCl,Therefore 3.65 moles of Hcl Requires 3.65Moles of NaOH and equivalence point is reached when that much is added to the acid being titrated for example .Half Eq point is when Half of the Solution being titrated has reacted. It is a point on a titration curve which corresponds to the addition of exactly half of the volume of the titrant needed to reach equivalence point (or end point )Corrected:So, at HALF-WAY Eq. point the pH = pKa, since the actual concentration of ACID is equal to concentration of its conjugate BASE because both are equal to HALF of the original (unknown) acid concentration to be titrated (half left = half formed).
What is the manipulated variable in a titration?
The manipulated variable would be the volume of the titrant (the thing thats being added). This is the only part of a titration that is altered. The responding variable would be the pH of the solution.
What are the applications of complexometric titration?
The Applications of Complexometric Titrations are as follows:1. Direct Titration: It is the simplest and the most convenient method in which thestandard solution of EDTA is slowly added to the metal ion solution till the endpoint is achieved. It is similar to simple acid-base titrations. For this method tobe useful the formation constant must be large and the indicator must provide avery distinct color change as mentioned earlier. Further we need standardizedsolution of EDTA and sometimes auxiliary complexing agents may be required.Some important elements which could be determined directly by thecomplexometric titration are Cu, Mn, Ca, Ba, Br, Zn, Cd, Hg, Al, Sn, Pb, Bi, Cr,Mo, Fe, Co, Ni, and Pd, etc. However, the presence of other ions may causeinterference and need to be suitably handled.2. Back Titration: In this method, an excess of a standard solution of EDTA isadded to the metal solution being determined so as to complex all the metal ionspresent in the solution. The excess of EDTA left after the complex formationwith the metal is back titrated with a standard solution of a second metal ion.This method becomes necessary if the analyte precipitates in the absence ofEDTA or reacts too slowly with EDTA, or it blocks the indicator. For example,determination of Mn is done by this method because a direct titration is notpossible due to precipitation of Mn (OH)2. The excess EDTA remaining aftercomplexation, is back titrated with a standard Zn solution using Eriochromeblack T as indicator. However, one has to ensure the standard metal ion shouldnot displace the analyte ion from their EDTA complex.3. Replacement Titration: When direct or back titrations do not give sharp endpoints or when there is no suitable indicator for the analyte the metal may bedetermined by this method. The metal to be analyzed is added to a metal-EDTAcomplex. The analyte ion (with higher Kf′) displaces EDTA from the metal andthe metal is subsequently titrated with standard EDTA. For example, in thedetermination of Mn an excess of Mg EDTA chelate is added to Mn solution.The Mn ions quantitatively displace Mg from Mg-EDTA solution because Mnforms a more stable complex with EDTA.Mn+ + MgY2 - (MY)(n - 4)+ + Mg2+The freed Mg metal is then directly titrated with a standard solution of EDTAusing Eriochrome black T indicator. Ca, Pb and Hg may also be determined bythis method.4. Indirect Titration: Certain anions that form precipitate with metal cations anddo not react with EDTA can be analyzed indirectly. The anion is firstprecipitated with a metal cation and the precipitate is washed and boiled with anexcess of disodium EDTA solution to form the metal complex.Mn+ + H2Y2 - (MY)(n - 4)+ + 2H+The protons from disodium EDTA are displaced by a heavy metal and titratedwith sodium alkali. Therefore, this method is also called alkalimetric titration.For example, barbiturates can be determined by this method.
Is The substance being dissolved in a solution is called a solvent.?
Nope - the substance being dissolved is the solute. The solution in which the substance is being dissolved - is the solvent.
In a solution the substance that is being dissolved is called the?
Solvent
How exactly do the businesses use titration?
Well I can only speak from my own experience - its only businesses where chemicals are involved- either being used in processes as in manufacturing or mining or steel making etc. Titration is used to determine the quantity of a chemical, maybe in an effluent or to check the strength of a solution in a processing tank.
How does titration of strong acid strong base differ from titration of weak acid strong base respect to quantity of base required to reach equivalent point?
There are three major differences between strong acid/strong base and weak acid/strong base titrations. For weak acid/strong base titrations: 1. The weak-acid solution has a higher initial pH. 2. The pH rises more rapidly at the start, but less rapidly near the equivalence point. 3. The pH at the equivalence point does not equal 7.00. (should be >7) In an acid-base titration, there is a 1:1 acid:base stoichiometry, so the equivalence point is the point where the moles of titrant added equals the moles of substance initially in the solution being titrated. Therefor the strength of the acid or base should not have an affect on the quantity of base required, only on the pH of the equivalence point. The number of moles of titrant and solution will have an effect on the quantity of base required.
What is a solution that is far from being saturated called?
water
