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NO2 consists of two oxygen atoms and one nitrogen atom per molecule. One oxygen is bonded to the nitrogen with a single covalent bond; the other is connected by two covalent bonds. Nitrogen dioxide is a radical; there is an uneven distribution of electrons, so one of these bonds is in resonance and moves between the two oxygens. See the related link for more information.

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Q: What is the structure of nitrogen dioxide?
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